2013-07-18
Variational Electrodynamics of Atoms
By
Progress In Electromagnetics Research B, Vol. 53, 147-186, 2013
Abstract
We generalize Wheeler-Feynman electrodynamics with a variational problem for trajectories that are required to merge continuously into given past and future boundary segments. We prove that the boundary-value problem is well posed for two classes of boundary data and the well-posed solution in general has velocity discontinuities, henceforth a broken extremum. Along regular segments, broken extrema satisfy the Euler-Lagrange neutral differential delay equations with state-dependent deviating arguments. At points where velocities are discontinuous, broken extrema satisfy the Weierstrass-Erdmann corner conditions that energies and momenta are continuous. Electromagnetic fields of the finite trajectory segments are derived quantities that can be extended to a bounded region B of space-time. Extrema with a finite number N of velocity discontinuities have extended fields defined in B with the possible exception of N spherical surfaces, and satisfy the integral laws of classical electrodynamics for most surfaces and curves inside B. As an application, we study the hydrogenoid atomic model with mass ratio varying by three orders of magnitude to include hydrogen, muonium and positronium. For each model we construct globally bounded trajectories with vanishing far-fields using periodic perturbations of circular orbits. Our model uses solutions of the neutral differential delay equations along regular segments and a variational approximation for the head-on collisional segments (spikes). Each hydrogenoid model predicts a discrete set of finitely measured neighbourhoods of periodic orbits with vanishing far-fields right at the correct atomic magnitude and in quantitative and qualitative agreement with experiment and quantum mechanics. The spacings between consecutive discrete angular momenta agree with Planck's constant within thirty-percent, while orbital frequencies agree with a corresponding spectroscopic line within a few percent.
Citation
Jayme De Luca, "Variational Electrodynamics of Atoms," Progress In Electromagnetics Research B, Vol. 53, 147-186, 2013.
doi:10.2528/PIERB13051207
References

1. Wheeler, J. A. and R. P. Feynman, "Interaction with the absorber as the mechanism of radiation," Reviews of Modern Physics, Vol. 17, 157, 1945.
doi:10.1103/RevModPhys.17.157        Google Scholar

2. Wheeler, J. A. and R. P. Feynman, "Classical electrodynamics in terms of interparticle action," Reviews of Modern Physics, Vol. 21, 425, 1949.
doi:10.1103/RevModPhys.21.425        Google Scholar

3. De Luca, J., "Variational principle for the Wheeler-Feynman electrodynamics," Journal of Mathematical Physics, Vol. 50, 062701, 2009.
doi:10.1063/1.3154509        Google Scholar

4. De Luca, J., "Minimizers with discontinuous velocities for the electromagnetic variational method," Physical Review E, Vol. 82, 026212, 2010.
doi:10.1103/PhysRevE.82.026212        Google Scholar

5. Gelfand, I. M. and S. V. Fomin, Calculus of Variations, Dover, New York, 2000.

6. Jackson, J. D., Classical Electrodynamics, 2nd Ed., John Wiley and Sons, New York, 1975.

7. Hale, J., Theory of Functional Differential Equations, Springer-Verlag, New York, 1977.

8. Bellen, A. and M. Zennaro, Numerical Methods for Delay Differential Equations, Oxford University Press, NY, 2003.

9. Hartung, F., T. Krisztin, H.-O. Walther, and J. Wu, Functional differential equations with state-dependent delays: Theory and applications, Vol. 3, Handbook of Differential Equations, Elsevier, Amsterdam, 2006.

10. Feynman, R., R. Leighton, and M. Sands, The Feynman Lectures on Physics, Vol. 2, Addison-Wesley Publishing, Palo Alto, 1964.

11. Fox, L. and The Numerical Solution of Two-point Boundary Problems in Ordinary Differential Equations, , Dover, New York, 1990.

12. Ascher, U. M. and L. R. Petzold, Computer Methods for Ordi-nary Differential Equations and Differential-algebraic Equations, SIAM, 1998.
doi:10.1137/1.9781611971392

13. Martin, J. L., General Relativity, Prentice Hall, London, 1995.

14. De Luca, J., A. R. Humphries, and S. B. Rodrigues, "Finite element boundary value integration of Wheeler-Feynman electrodynamics," Journal of Computational and Applied Mathematics, Vol. 236, 3319-3337, 2012.
doi:10.1016/j.cam.2012.02.039        Google Scholar

15. Gordon, W., "A minimizing property of Keplerian orbits," American Journal of Mathematics, Vol. 99, 961, 1977.
doi:10.2307/2373993        Google Scholar

16. Brezis, H., Functional Analysis, Sobolev Spaces and Partial Differential Equations, Springer, New York, 2010.

17. Jabri, Y., The Mountain Pass Theorem, Cambridge University Press, Cambridge, 2003.

18. Currie, D. G., T. F. Jordan, and E. C. G. Sudarshan, "Relativistic invariance and hamiltonian theories of interacting particles," Reviews of Modern Physics, Vol. 35, 350, 1963.
doi:10.1103/RevModPhys.35.350        Google Scholar

19. Marmo, G., N. Mukunda, and E. C. G. Sudarshan, "Relativistic particle dynamics-Lagrangian proof of the no-interaction theorem," Physical Review D, Vol. 30, 2110, 1984.
doi:10.1103/PhysRevD.30.2110        Google Scholar

20. Schild, A., "Electromagnetic two-body problem," Physical Review, Vol. 131, 2762, 1963.
doi:10.1103/PhysRev.131.2762        Google Scholar

21. Staruszkiewicz, A., "On stability of a circular motion in the relativistic Kepler problem," Acta Physica Polonica, Vol. XXXIII, 1007, 1968.        Google Scholar

22. Andersen, C. M. and H. C. von Baeyer, "Almost circular orbits in classical action-at-a-distance electrodynamics," Physical Review D, Vol. 5, 2470, 1972.
doi:10.1103/PhysRevD.5.2470        Google Scholar

23. De Luca, J., "Stiff three-frequency orbit of the hydrogen atom," Physical Review E, Vol. 73, 026221, 2006.
doi:10.1103/PhysRevE.73.026221        Google Scholar

24. Andersen, C. M. and H. C. von Baeyer, "Circular orbits in classical relativistic two-body systems," Annals of Physics, Vol. 60, 67-84, 1970.
doi:10.1016/0003-4916(70)90482-3        Google Scholar

25. Von Baeyer, H. C., "Semiclassical quantization of the relativistic Kepler problem," Physical Review D, Vol. 12, 3086, 1975.
doi:10.1103/PhysRevD.12.3086        Google Scholar

26. Bohr, N., "On the constitution of atoms and molecules," Philosophical Magazine, Vol. 26, No. 1, 1913; Vol. 26, 476, 1913.        Google Scholar

27. Bethe, H. A. and E. E. Salpeter, Quantum Mechanics of One- and Two-electron Atoms, Dover, New York, 2008.

28. ter Haar, D., The Old Quantum Theory, Pergamon Press, New York, 1967.

29. De Luca, J., "Double-slit and electromagnetic models to complete quantum mechanics," Journal of Computational and Theoretical Nanoscience, Vol. 8, 1040-1051, 2011.
doi:10.1166/jctn.2011.1782        Google Scholar

30. Dirac, P. A. M., "Classical theory of radiating electrons," Proceedings of the Royal Society of London, Ser. A, Vol. 167, 148, 1938.
doi:10.1098/rspa.1938.0124        Google Scholar

31. De Luca, J., "Electrodynamics of Helium with retardation and self-interaction effects," Physical Review Letters, Vol. 80, 680, 1998.
doi:10.1103/PhysRevLett.80.680        Google Scholar

32. De Luca, J., "Electrodynamics of a two-electron atom with retardation and self-interaction," Physical Review E, Vol. 58, 5727, 1998.
doi:10.1103/PhysRevE.58.5727        Google Scholar

33. Mehra, J., The Beat of a Di®erent Drum: The Life and Science of Richard Feynman, Clarendon Press, Oxford, 1994.

34. Aharonov, Y. and D. Bohm, "Significance of electromagnetic potentials in the quantum theory," Physical Review, Vol. 115, 485, 1959.
doi:10.1103/PhysRev.115.485        Google Scholar